This demonstration can easily be used as a student lab.Soak wooden splints or cotton swabs in deionized water for a few hours and then dip them into small samples of each solid before putting them through the flame.If you cannot find wooden splints you can substitute generic cotton swabs, or longer craft swabs.Allow the splints to sit in the solutions overnight.Distribute the remaining wooden splints between the solutions.Use a separate wooden splint to stir each of the solutions.Note: if you do not have 100 mL beakers, substitute another piece of glassware and use a 50 mL graduated cylinder to add the deionized water.Add deionized water up to the 50 mL mark.7.9 grams of Strontium Chloride (SrCl 2).8.5 grams of Copper Chloride (CuCl 2*2H 2O).12.2 grams of Barium Chloride (BaCl 2*2H 2O) - Note: Barium chloride is highly toxic.Add the solid metallic salts to the beakers:.Label each of the 100 mL beakers with the name of the salt that it will hold.If you need to make ≈1.0M solutions of the metallic salts follow these instructions: Read a Safety Alert from the American Chemical Society about the traditional procedure for this demonstration.The American Chemical Society Committee on Chemical Safety recommends that this method be discontinued immediately. The traditional Rainbow Demonstration required that a highly flammable solvent, such as methanol or ethanol, be mixed with the metallic salts. This procedure is an updated version of the traditional one.The purpose is to demonstrate to students the variety of colors produced when different metals or metallic salts meet a flame. The Rainbow Demonstration (or Rainbow Flame Demonstration) is an activity popularly conducted in chemistry classrooms.Wash hands after handling materials used to prepare for or perform this experiment.Do not reach over it, tie back hair, and secure loose clothing. Keep flames away from flammable substances. Always use caution around open flames.Wear proper personal protective equipment when preparing and working with solutions.Safety goggles and lab apron are required. Students should wear proper safety gear during chemistry demonstrations.250 mL beaker or plastic or cardboard cup half full of waterĬopies of the visible light spectrum chart showing wavelength and frequency values.50 mL of 1.0M Strontium Chloride (SrCl 2).50 mL of 1.0M Calcium Chloride (CaCl 2).50 mL of 1.0M Barium Chloride (BaCl 2) - Note: Barium chloride is highly toxic.Wooden splints (number depends upon how many times the demo will be performed).Teacher Preparation: 30 minutes, longer if solution preparation is necessary This lesson supports students’ understanding of Identify an unknown metal by the color it emits when passed through a flame.Calculate the wavelength of light given its frequency.Calculate the frequency of light given its wavelength.Use flame tests to identify a metal or metallic salt by the color that it produces when it is put into a flame.HS-PS4-3: Evaluate the claims, evidence, and reasoning behind the idea that electromagnetic radiation can be described either by a wave model or a particle model, and that for some situations one model is more useful than the other.īy the end of this demonstration, students should be able to.HS-PS4-1: Use mathematical representations to describe a simple model for waves that includes how the amplitude of a wave is related to the energy in a wave.This activity will help prepare your students to meet the performance expectations in the following standards: In this demonstration, students will observe the variety of colors produced when different metals or metallic salts are heated in a flame.
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Were also updated with more official cheats from. Look to the bottom of the list for expansion-specific information. Weve also listed cheats for Get to Work and other Expansion Packs. Remember to disable testing cheats enter "testingCheatsEnabled false" into the console before you resume the game. This is a huge, curated list of cheats in The Sims 4 that allow you to get money, prevent death, and adjust your Skill and Career levels. A white text box will appear at the top of the screen. Hold down the following 3 keys on your keyboard at the same time, Ctrl + Shift + C. Alternatively, you can type in the less concise syntax "sims.modify_funds x" to add or remove a specified amount. The Sims 4 Money Cheats (Unlimited Money) Before you can use the cheat codes you’ll need to bring up the Cheat Console. For example, if the family has 50,000 Simoleons, you can enter "money 25000" to immediately change the balance to 25,000 Simoleons. This will also work to remove unwanted funds. If there's a certain amount of money you're interested in having, open the console, type in "testingCheatsEnabled true" and press "Enter." After this, enter "money x," replacing "x" with the amount of money the family will have. If your must-have purchase requires a little more dough, try "motherlode" instead this code cranks the monetary reward up to 50,000 Simoleons - halfway to reaching your Sim's fortune aspiration if he has one. Type in either "rosebud" or "kaching" and press "Enter" to quickly add 1,000 Simoleons to the total family funds. Once you've loaded a game and household, you can press "Shift+Ctrl+C" to open the cheat console. Low-frequency loudspeaker featuring one 5.25" (133 mm) woofer that delivers deep, non-localized bass support down to 40 Hz without audible distortion.Features one 5.25" (133 mm) woofer that delivers deep bass down to 40 Hz without audible distortion. Classy and sleek modular design that allows either 2 or 4 satellites per bass module and simple connection of parallel bass modules.Bose FreeSpace 3 Series II Acoustimass Subwoofer Module - Whiteĭesigned to provide flush-mount bass augmentation for new and existing background music systems. Communications Ports RS-232 (DB9M, DTE), Bose CC-16 (3.81 mm Phoenix Contact, 3-pin) q Analog audio connectors Mic/line-level balanced input and line-level output connectors w. 360-degree sound coverage for our widest outdoor. The subwoofer is also plenum rated, for use in air handling spaces, when. Configure to mono or stereo depending on your needs. Connect them to your existing stereo receiver and enjoy natural sound throughout a broad listening area. connections for 2 or 4 Bose FreeSpace 3 satellite speakers (sold separately). You can select 70/100V or low impedance with the onboard transformer that has an intuitive wheel adjustment. 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They feature a wide coverage pattern and perform down to a frequency response of 40 Hz for clear, distortion-free bass, even at very low levels. 3 flush and surface satellite speakers, or existing systems where additional bass reinforcement is desired Module design allows parallel connection of. This satellite system features four Bose 40143 satellite speakers that sit flush for almost invisible installation and can easily be moved and reworked for a variety of layouts. The Bose FreeSpace 3 surface-mount satellites are high-performance, extended-range loudspeakers designed for small to medium-sized installed applications. No screeching or audible button clicks as you switch between channels. Then, when you need to make announcements and pages, you can be assured that they will be crisp and distortion free. If you need a high performing sound solution in a small to medium space, then this satellite system is for you. The system will give you an even distribution across your entire space. When mounting adjacent to heat-generating products such as power amplifiers, allow a 1RU open space between the SP-24 sound processor and the amplifier to allow for air flow. Transform your customer's shopping experience by providing rich and vibrant background music that doesn’t distract from conversation and browsing. Important Safety Information Installation and Safety Guidelines English. The Bose FreeSpace 3 Subwoofer Satellite Surface Mount System in white is ideal if you want a system that can grow with you and your business needs. Ideal for zone-expansion applications, Bose Professional PowerSpace amplifiers enhance any premium commercial sound installation with clean, reliable power and digital connectivity. GPIO slot 2 For optional 2nd GPIO card 2. Eight general purpose control outputs These are inputs S1-1 through S1-4, and S3-1 through S3-4 in the ControlSpace Designer software. This sound solution from Bose is particularly suited to small and medium retail stores with the possibility to mix, match and expand with additional Bose products. : Rear Panel Controls And Connections Eight general purpose control inputs connectors are green) in slots 1 and 3. #11,, ©NBC Revolution, Tracy Spiridakos (L), Elizabeth Mitchell (R), 'The Stand', Season 1, Ep. #14,, ©NBC Revolution, Tracy Spiridakos, 'The Stand', Season 1, Ep. #13,, ©NBC Revolution, Tracy Spiridakos, 'The Night Lights Went Out In Georgia', Season 1, Ep. #13,, ©NBC Revolution, Tracy Spiridakos, 'The Song Remains The Same', Season 1, Ep. Pardo (R), 'The Song Remains The Same', Season 1, Ep. #14,, ©NBC Revolution, Tracy Spiridakos (L), J.D. Externally, she’s been investigating a case involving human trafficking and the son of the new precinct chief. Internally, she’s been dealing with the emotional fallout of her husband, Halstead (Jesse Lee Soffer), deciding to leave and fight drug cartels in Central America. Pardo (R), 'The Song Remains The Same', Season 1, Ep. Upton (Tracy Spiridakos) has been doing a lot on Chicago PD lately. #14,, ©NBC Revolution, Tracy Spiridakos, 'The Song Remains The Same', Season 1, Ep. #14,, ©NBC Revolution, Tracy Spiridakos, 'The Night Lights Went Out In Georgia', Season 1, Ep. #14,, ©KSITE Revolution, Daniella Alonso (L), Tracy Spiridakos (R), 'The Night Lights Went Out In Georgia', Season 1, Ep. #6,, ©SHO Revolution, Daniella Alonso (L), Tracy Spiridakos (R), 'The Night Lights Went Out In Georgia', Season 1, Ep. #6,, ©SHO Episodes, Tracy Spiridakos (L), Matt LeBlanc (R), 'Episode 306', Season 3, Ep. #6,, ©SHO Episodes, Mircea Monroe (L), Tracy Spiridakos (R), 'Episode 306', Season 3, Ep. #6,, ©SHO Episodes, Matt LeBlanc (L), Tracy Spiridakos (R), 'Episode 306', Season 3, Ep. Photo By: Priscilla Grant/Everett Collection Episodes, Tracy Spiridakos (L), Matt LeBlanc (R), 'Episode 306', Season 3, Ep. Show Less Show More Photos Tracy Spiridakos at arrivals for TCA Summer Press Tour: NBC Universal, The Beverly Hilton Hotel, Beverly Hills, CA August 3, 2017. In 2012, Spiridakos relocated to the United States to take on the role of determined, crossbow-wielding survivor Charlie Matheson on the hit adventure series "Revolution" (NBC, 2012-14), executive produced by J.J. Spiridakos became a familiar face in Vancouver-based television productions, most notably appearing in the recurring role of vengeful werewolf Brynn MacLean on the American adaptation of the BBC series "Being Human" (Syfy, 2011- ). Supporting roles in Canadian-produced TV movies "Web of Desire" (2009) and "Goblin" (2010) followed, as well as a lead in the independent feature film "The Boy She Met Online" (2010). Spiridakos moved to Vancouver, British Columbia, Canada in 2007 to pursue acting and quickly found work in small roles on such television series as "Supernatural" (The WB, 2005-06 The CW, 2006- ) and "The L Word" (Showtime, 2004-09), eventually landing her first lead role by voicing 15-year-old mayor Becky Richards on the animated series "Majority Rules!" (Teletoon Canada, 2009). Tracy Spiridakos was born in Winnipeg, Manitoba, Canada in 1992, and spent part of her childhood growing up in a small village in Greece. It can create some tension but it does create trust.Canadian actress Tracy Spiridakos could easily have played light, romantic leads and dizzy comedic roles, but it was her embodiment of fierce, capable and often troubled characters, including the lead role of Charlie Matheson on the post-apocalyptic series "Revolution" (NBC, 2012-14), that established her as a talent to be taken seriously. Hailey, even though they might clash, she stands up for herself and isn’t afraid to say who she is and what she thinks. “One thing that Voight insists on and admires - and it’s hard for his team to do - is he always wants you to be you. “We have had more intimate moments, and when I say intimate, I mean personal revelations,” Beghe says. Her work relationship, though, is growing with Voight (Jason Beghe), who also lost his right-hand man at work when Halstead left. As far as a relationship and even getting close to people, I can see her being somebody that will keep people at a distance while she’s going through what she’s going through.” “On a personal level, I can imagine that there’s gonna be a part of her that shuts down emotionally. I feel like that is her trajectory,” she says. “I do think she is becoming a better cop. Although she’s making many “adjustments” in her personal life, Hailey’s put all her focus into work. While Liga MX gets much higher ratings than MLS, leaders of both leagues hope they can grow their partnership and boost revenue. Sports Soccer newsletter: Liga MX president Mikel Arriola turns to MLS to spur growth While Mexican fans on both sides of the border defended their country’s values and soccer on social media, they also leveled criticism at official reaction to the violence. A Mets fan was beaten in the same parking lot and nearly died four years later. Nationalism, meanwhile, fed a wave of bloody violence during the 2016 European Championships in France.Īnd in Los Angeles, Bryan Stow, a Giants baseball fan, nearly died after being beaten in the parking lot at Dodger Stadium. In France and England, hooliganism often has been triggered by social tensions, with violence once so commonplace in the United Kingdom that it was referred to as the English Disease, and women and children were dissuaded from attending games. In many Baltic countries, supporter groups have long been havens for fascist and paramilitary groups who use team affiliation as a cover for attacking political rivals. The government shut down the country’s domestic soccer league for two years in response. Ten years ago, a riot in an Egyptian stadium left 74 people dead and more than 500 others injured. More than 50 countries on six continents have seen some level of soccer hooliganism. “We understand that that’s a problem, but it’s not just a brown people problem,” said Sergio Tristan, an attorney in Austin, Texas, and the founder of Pancho Villa’s Army, the largest organized group of Mexican soccer fans in the U.S. While coping with the violence, fans on social media defended their country in response to those who attributed the brawl to a violent Mexican culture. The Mexico City newspaper El Universal called it “the darkest day for Mexican soccer.” Why a more robust security presence wasn’t on site for a match between teams with a recent history of fan violence certainly will be addressed in the multiple investigations being promised.Īlso to be addressed is why barriers meant to separate the rival supporter groups were easily breached after fighting began in the stands, allowing the violence to spill onto the field. Querétaro club president Gabriel Solares said during a news conference that there were 600 security personnel in a stadium that seats nearly 34,000 people. Most, if not all, of the people who were hospitalized were Atlas supporters.īlame also was leveled at the stadium’s lax security detail, which was largely made up of privately contracted officers who were slow to react and ineffective at controlling the violence. Blame for the violence fell mostly with hard-core Querétaro fans, known as barras bravas, or fierce gangs, in Spanish.
Soon after the WorldStar posting of the L-train fight, the vid was picked up by more mainstream sites like Gothamist, which, despite some tsk-tsk dissing of WSHH as “an Internet cesspool that’s cashed in big on senseless fight videos,” was happy enough (as was ) to make Daniel Endara’s pain available to its better-heeled breed of voyeurs. It has certainly influenced the news cycle. Few if any express sympathy for the humiliated, knocked-out, or stone-cold-dead individuals seen in the videos.Īs evidenced by last week’s posting, “ These Cops in the Bronx NY Are Out of Control!,” in which four large NYPD officers engage in a Rodney King–style beating of a suspect (resulting in the cops losing their guns and badges), the WSHH meme is having an effect well beyond the Net. Instead, you whip out your smartphone, vid the action, and upload it on WorldStar.Īccompanied by the sort of tabloid-headline writing that would make any Australian phone hacker swoon, videos run by WSHH in the past several months include “ Foolery: Off-Duty McDonald’s Manager Fired After Punching a Mother With Autistic Kids for Bringing a Guide Dog in Restaurant!” “ Police Kill Deaf Cyclist With Stun Gun!” “ 41 Deep Brawl, Guys Getting Jumped for Talking About There Baby Moms (Granny Came Out With the Shovel and Broom)!” and “ Lesbian Street Fight in ATL!” Most WSHH entries elicit hundreds of typically scabrous, grammatically eccentric, N-word-intensive comments. This is what it has come to: No longer do individuals sit idly by and watch a fellow citizen get attacked, as bystanders allegedly did in 1964, when Kitty Genovese was murdered outside her Kew Gardens apartment house. Obviously, you don’t have to be Jean Baudrillard to know a WSHH video in the making when you see one. Still, it wasn’t until Daniel Endara’s L‑train stomping that WorldStar went meta. With new vids constantly on display, a large portion of WSHH viewers, many hailing from the 18-to-34 male-demographic sweet spot, say they check the site at least once a day. This was ahead of Slate, CBS, and Merriam-Webster, and right behind Sprint and Travelocity. With 1.1 million people visiting the site’s archaically funky layout per day, WSHH, as of last week, was ranked the 278th-most-visited URL in the U.S., according to Alexa, a web-traffic-tracking service. Over the years, however, the site has separated itself from the competition by depicting what founder Lee “Q” O’Denat, a self-confessed “Haitian ghetto nerd” from Hollis, Queens, calls “the whole gamut A-to-Z soup-to-nuts the good, the bad, and the ugly of the urban experience.” From WorldStar’s POV, this includes a daily array of street fights and pushing matches in project hallways and camera scans of shoplifting incidents. “WorldStar,” for those who don’t know, is, which started in 2005 as just one more semi-swag hip-hop blog eventually featuring homemade videos of rappers and “sticky page” pix of buxom ladies. What made this video different from the usual mélange of sucker punches and overlit swish pans was the voice on the soundtrack, the one that shouted, “WorldStar, baby!” In the ensuing mayhem, Endara was beaten with fists and kicked to the floor. Several of the shirtless man’s confederates converged on the scene. It was then, as shown in the one-minute-and-27-second recording of the event, that one of the teens, wearing no shirt despite the wintry weather, confronted Endara, who pushed him away. on November 8, 2011, when, with the train approaching the Myrtle/Wyckoff station, 25-year-old security guard Daniel Endara admonished a number of teenagers for spitting on the subway-car floor. The infamous L-train subway-fight footage.įor students of Internet subway-fight videos, the genre entered a new realm of virality a couple of months ago on the L train. In case any of you think I'm just being a cranky motherfucker Mike Moreno echoed similar sentiments at a clinic at the University of New Orleans. I get that getting legal PDF fakebooks and an iPad is an initial expensive investment, but the irony here is many if not most of the good young players, like this bassist, are already spending multiple thousands of dollars on college, and you can get an accurate library of hundreds of standards and a reconditioned iPad for a few hundred dollars. After one tune I said "if you ever play this tune again there are some hits that are part of the form that you may want to know." His response was "I've never heard that tune before," which pretty much proves my point if you don't know a tune and you're trying to play it from a shitty chart you're going to fuck it up. Several times I said to him "I have the chart right here" and he ignored me. When that happened the bassist pulled them up on his phone, but I was right next to him with an iPad with PDF charts culled from the Chuck Sher New Real books and other vetted sources. There were a lot of the leader's original tunes and ones from other composers he had charts on, but he also called some standards. I was working with a bandleader for the first time and he had a young bassist - a very good player - who I'd only ever played with once before. Here's what happened on my gig last night: The tunes are crowd sourced and you get what you pay for. The collections of tunes in the the iReal are the same but worse there are so many bad changes in those that it's ridiculous, plus you have none of the other useful info like melodies, bass lines, rhythm section hits, and so on. That book was compiled by students at Berklee and that's why there were so many errors they didn't have the skills yet to transcribe the music accurately. I grew up when the Real Book filled this function, but I was warned early on by older musicians not to rely on it too much because of how many errors there were in it. Obviously it's a super handy app to have and there are times when it's a useful tool, but if you're using it as your default way of getting through gigs you're being a slacker. These days it seems like everyone uses the iReal Pro for basic charts on gigs. I developed this recipe because it’s hard to go out during this pandemic, and I really felt like some sweet cream-ppang. When I was a kid I used to eat both of these all the time, and even though so many trends have come and go, they are still among the top sellers! Since as long as I can remember it’s been one of the most popular items in Korean bakeries, along with a sweet red bean-filled bread called danpat-ppang. “It’s a perfect combination of two of my favorite sweets – doughnuts and ice cream.”Īsked when he’d return, Hernandez laughed and said, “Tomorrow.Today’s recipe is cream-ppang custard cream filled bread, one of my favorite pastries at any Korean bakery. “It’s unique and something different,” said Hernandez, who was at the Fountain Valley shop. Steven Hernandez of La Mirada is a big fan. We just want to continue offering customers an experience in a nontraditional way,” he said. “The goal is to just keep people excited. “We feel like we need to keep it updated with culture, fashion and lifestyle,” Nghiem said. The Fountain Valley location has the original black and white design, but will be remodeled soon. “You get overwhelmed when you see all these flavors you aren’t familiar with,” Espajo said. She has even posted photos of her treats to her Instagram feed. Nicole Espajo of Garden Grove, who was at the Fountain Valley shop enjoying an unglazed Milky Bun with Cookie Monster ice cream, said she heard about Afters through social media. “We took what we liked and adapted them to the current culture.” “We used flavors that we grew up eating,” Nghiem said. Nghiem and Nguyen created the ice cream flavors, ranging from the most popular, Cookie Monster, which is blue cookies and cream, to jasmine milk tea. They understood what we were trying to do,” Nghiem said. You can get a Milky Bun for $5, with extra toppings ranging from cereal to mochi for 50 cents each. The result is a warm bun on the outside and frozen ice cream inside. The Milky Bun is bigger than a doughnut, has no holes and is denser so it can be heated while the ice cream inside stays cold.Īfters uses a “secret” patented press with metal plates to seal the bun and its contents, according to Nghiem. They came up with at least 15 formulas before settling on the one that became the Milky Bun. Once they had the ingredients for their unique ice cream sandwich, they had to develop a process to make the final product. “I asked him – ‘What do you think?’ and he said ‘This is it,’” Nghiem recalled. They got some ice cream and tried the combination. He bought a few doughnuts and took them to Nguyen. Then, a month before the shop was scheduled to open, Nghiem drove past a doughnut store and the idea clicked. They tried a variety of combinations for their ice cream sandwiches ranging from white bread to sweet Hawaiian rolls, but none tasted right. “We knew we had to do well at home before we brought it anywhere else,” Nguyen said. Their goal of reinventing the ice cream sandwich took a little longer than expected. “Afters is a noun for dessert in European countries,” Nghiem said. “Dessert was always something we shared a passion for, so that became the premise for what we wanted to do.” “As we got older, we noticed a need for more nightlife in our area,” Nghiem said. Once approval is granted, you would have 2 weeks from approval date to return the pillow to be eligible for a refund. All return shipping costs are the responsibility of the customer. tears, rips, stains, damaged material from the washer and/or dryer, etc.), would automatically void the return policy. If after sleeping on the pillow for 30 nights you decide the pillow isn't right for you, just email us at your order number so we can start the return process. Proper sleep posture can help you sleep deeper and longer, so you can get the sleep you need to have a day that is more energized and with better focus. Jason Loth, believes that spinal alignment is where is all begins. Your body also may need time to adapt to your new pillow since most people have never slept in correct posture. There are many benefits to restorative sleep, and co-founder of SpineAlign, Dr. Your muscles are sore for a little while until they are used on a regular basis. This is similar to going to the gym for the first time. Any returns before the 30-night trial is over will result in a 25% re-stocking fee. The 30-night trial allows your body ample time to adjust to the feel of sleeping in correct posture, something that most people have never experienced and can take a little time to get used to. However, we do ask that you sleep on your pillow for a minimum of 30 nights before requesting a return. |
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